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research article

Lattice dynamics and antiferroelectricity in PbZrO3 tested by x-ray and Brillouin light scattering

Burkovsky, R. G.
•
Tagantsev, A. K.  
•
Vaideeswaran, K.
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2014
Physical Review B

We report the results of a comprehensive study of the critical dynamics of the classical perovskite antiferroelectric PbZrO3. The combination of inelastic x-ray and diffuse x-ray scattering techniques and Brillouin light scattering was used. It is found that the dispersion of the transverse acoustic (TA) phonons is strongly anisotropic. The dispersion curve of the in-plane polarized TA phonons propagating in [1 1 0] direction demonstrates pronounced softening. Slowing down of the excitations at R point is found, it is manifested in growing of the central peak. This slowing down is too weak to be considered as a primary origin of the corresponding order parameter. Obtained results are treated in terms of TA-transverse optic (TO) flexoelectric mode coupling. It is demonstrated that the structural phase transformation in PbZrO3 can be considered as the result of the only intrinsic instability associated with the ferroelectric soft mode.

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Type
research article
DOI
10.1103/PhysRevB.90.144301
Web of Science ID

WOS:000344006500001

Author(s)
Burkovsky, R. G.
Tagantsev, A. K.  
Vaideeswaran, K.
Setter, N.  
Vakhrushev, S. B.
Filimonov, A. V.
Shaganov, A.
Andronikova, D.
Rudskoy, A. I.
Baron, A. Q. R.
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Date Issued

2014

Publisher

American Physical Society

Published in
Physical Review B
Volume

90

Issue

14

Article Number

144301

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
December 30, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/109810
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