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  4. Flexible and Binder-Free Iron Phosphide Electrodes Using a Three-Dimensional Support for High Hydrogen Productivity
 
research article

Flexible and Binder-Free Iron Phosphide Electrodes Using a Three-Dimensional Support for High Hydrogen Productivity

Diez-Garcia, Maria Isabel  
•
Garcia Blanco, Andres Alberto
•
Murcia-Lopez, Sebastian
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May 10, 2023
Chemelectrochem

In this work, an inexpensive and reliable microstructured electrode for the hydrogen evolution reaction (HER) is developed. This cathode is made of Earth-abundant elements consisting of iron phosphide as an electrocatalyst and carbon felt (CF) as a flexible conductive scaffold. Its porous character and binder-free FeP coverage over the carbon fibers generate a high number of accessible active sites for the reaction, achieving a high value of the electrochemically active surface area. The electrode reaches 100 mA center dot cm(-2) by applying only 53 mV vs RHE at 50 degrees C in 0.5 M H2SO4, demonstrating excellent electrocatalytic activity for the HER and outstanding stability in acidic electrolyte. Furthermore, the feasibility of these electrodes for industrial application is evaluated using a PEM electrolyzer. The developed prototype with a cathodic area of 1.8 cm(2) shows a very promising performance, reaching 14.9 mmol H-2 center dot h(-1) center dot cm(-2) (corresponding to 800 mA center dot cm(-2)) at a voltage of only 2.1 V.

  • Details
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Type
research article
DOI
10.1002/celc.202201152
Web of Science ID

WOS:000985081100001

Author(s)
Diez-Garcia, Maria Isabel  
Garcia Blanco, Andres Alberto
Murcia-Lopez, Sebastian
Botifoll, Marc
Arbiol, Jordi
Qamar, Mohammad
Morante, Joan Ramon
Date Issued

2023-05-10

Published in
Chemelectrochem
Article Number

e202201152

Subjects

Electrochemistry

•

Electrochemistry

•

carbon felt

•

hydrogen evolution reaction

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fep nanoparticles

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pem electrolyzer

•

water splitting

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fep nanoparticles

•

evolution cathode

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carbon cloth

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electrocatalysts

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efficient

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catalysts

•

felt

•

film

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

Available on Infoscience
July 3, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/198758
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