Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Dynamics of supercooled liquids: Density fluctuations and mode coupling theory
 
research article

Dynamics of supercooled liquids: Density fluctuations and mode coupling theory

Zaccarelli, E.
•
Foffi, G.  
•
De Gregorio, P.
Show more
2002
Journal of Physics: Condensed Matter

We write equations of motion for density variables that are equivalent to Newton's equations. We then propose a set of trial equations parametrized by two unknown functions to describe the exact equations. These are chosen to best fit the exact Newtonian equations. Following established ideas, we choose to separate these trial functions into a set representing integrable motions of density waves, and a set containing all effects of non-integrability. The density waves are found to have the dispersion of sound waves, and this ensures that the interactions between the independent waves are minimized. Furthermore, it transpires that the static structure factor is fixed by this minimum condition to be the solution of the Yvon-Born-Green equation. The residual interactions between density waves are explicitly isolated in their Newtonian representation and expanded by choosing the dominant objects in the phase space of the system, that can be represented by a dissipative term with memory and a random noise. This provides a mapping between deterministic and stochastic dynamics. Imposing the fluctuation-dissipation theorem allows us to calculate the memory kernel. We write exactly the expression for it, following two different routes, i.e. using explicitly Newton's equations, or instead, their implicit form, that must be projected onto density pairs, as in the development of the well established mode coupling theory. We compare these two ways of proceeding, showing the necessity to enforce a new equation of constraint for the two schemes to be consistent. Thus, while in the first 'Newtonian' representation a simple Gaussian approximation for the random process leads easily to the mean spherical approximation for the statics and to MCT for the dynamics of the system, in the second case higher levels of approximation are required to have a fully consistent theory.

  • Details
  • Metrics
Type
research article
DOI
10.1088/0953-8984/14/9/330
Scopus ID

2-s2.0-0037061154

Author(s)
Zaccarelli, E.
Foffi, G.  
De Gregorio, P.
Sciortino, F.
Tartaglia, P.
Dawson, K.A.
Date Issued

2002

Published in
Journal of Physics: Condensed Matter
Volume

14

Issue

9

Start page

2413

End page

2437

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
GR-FO  
Available on Infoscience
January 27, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/46235
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés