Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Conferences, Workshops, Symposiums, and Seminars
  4. Measurement-Based Drift Correction in Spectroscopic Calibration Models
 
conference paper

Measurement-Based Drift Correction in Spectroscopic Calibration Models

Gujral, Paman
•
Amrhein, Michael  
•
Bonvin, Dominique  
2008
11th Conference on Chemometrics in Analytical Chemistry
11th Conference on Chemometrics in Analytical Chemistry (CAC), 2008

Correct prediction of analyte concentrations from a new spectrum without drift is possible provided the spectrum lies in the row space spanned by the calibration spectra (space-inclusion condition). However, this condition may be violated as on-line spectrometers are compromised by instrumental, process and operational drifts that are not seen during calibration. A space- inclusion condition, which new spectra possibly corrupted with drift should fulfill, is proposed for drift-correction methods. These methods are characterized as either explicit or implicit based on whether or not drift is estimated using on-line reference measurements. A property of the kernel used in explicit methods is proposed based on the space-inclusion condition. The results are illustrated with a simulation study that uses mathematical models for different drift types.

  • Files
  • Details
  • Metrics
Loading...
Thumbnail Image
Name

4CAC.pdf

Access type

openaccess

Size

78.67 KB

Format

Adobe PDF

Checksum (MD5)

e66833d3111dc7d22cd3669330ee31cc

Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés