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research article

Rotation-induced recovery and bleaching in magnetic resonance

Linde, Angel J. Perez  
•
Chinthalapalli, Srinivas  
•
Carnevale, Diego  
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2015
Physical Chemistry Chemical Physics

Thurber and Tycko recently described a 'bleaching effect' that occurs in magnetic resonance when solid samples that are doped with paramagnetic agents are subjected to rotation by magic angle spinning (MAS) in a static magnetic field with a rotation period comparable to the longitudinal relaxation time T-1e of the electron spins. The bleaching effect has been investigated by Thurber and Tycko in samples spinning at temperatures near 20 K in a field of 9.4 T and by Corzilius et al. near 80 K in a field of 4.9 T. In our experience, the bleaching effect is not very severe at temperatures near 100 K in a field of 9.4 T at spinning frequencies up to 12 kHz. Bleaching can partly cancel DNP enhancements that are normally evaluated by comparing signal intensities with and without microwave irradiation. The signal attenuation due to doping and sample rotation is usually not taken into consideration when defining enhancement factors. In this paper, we describe a novel observation that the rotation of glassy samples doped with lanthanides spinning at frequencies as low as 0.1 kHz can lead to a significant reduction of the spin-lattice relaxation times T-1(H-1) of protons. This effect, which bears similarities with the so-called spin refrigerators, may contribute to the success of 'brute force polarization' at sample temperatures in the mK range. The acceleration of longitudinal proton relaxation also allows one to improve the signal-to-noise ratio per unit time.

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Type
research article
DOI
10.1039/c4cp05735j
Web of Science ID

WOS:000351435300029

Author(s)
Linde, Angel J. Perez  
Chinthalapalli, Srinivas  
Carnevale, Diego  
Bodenhausen, Geoffrey  
Date Issued

2015

Publisher

Royal Society of Chemistry

Published in
Physical Chemistry Chemical Physics
Volume

17

Issue

9

Start page

6415

End page

6422

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRMB  
Available on Infoscience
May 29, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/114496
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