Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Measurement of transverse relaxation in coupled spin systems by semi-selective refocusing: evidence for interference of CSA and dipolar relaxation
 
Loading...
Thumbnail Image
research article

Measurement of transverse relaxation in coupled spin systems by semi-selective refocusing: evidence for interference of CSA and dipolar relaxation

Emsley, L.  
•
Kowalewski, J.
•
Bodenhausen, G.  
1990
Applied Magnetic Resonance

A novel spin-echo expt. is proposed that uses semiselective Gaussian pulse cascades for refocusing in systems with homonuclear couplings. The expt. allows one to obtain evdience of differential T2 effects due to cross-correlation of proton chem. shift anisotropy and proton-proton dipolar interactions in a small arom. compd. at 9.4 T. The spin-echo expt. was applied to measure transverse relaxation rates for selected multiplets of the cyclic undecapeptide cyclosporin. Possible extensions to multiple-quantum spin echo-spectroscopy are indicated. [on SciFinder (R)]

  • Details
  • Metrics
Type
research article
DOI
10.1007/BF03166151
Author(s)
Emsley, L.  
•
Kowalewski, J.
•
Bodenhausen, G.  
Date Issued

1990

Published in
Applied Magnetic Resonance
Volume

1

Issue

2

Start page

139

End page

47

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRMB  
LRM  
Available on Infoscience
February 22, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/225538
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés