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research article

An asymmetric total synthesis of sanjoinine G1

Laib, Taoues
•
Zhu, Jieping  
1999
Tetrahedron Letters

A convergent total synthesis of sanjoinine G1 (I), a 14-membered cyclopeptide alkaloid was described. Formation of aryl alkyl ether bond with concomitant construction of macrocycle by way of an intramol. SNAr reaction was the key step in this synthesis. Only two conventional peptide coupling steps were required for the prepn. of the cyclization precursor. [on SciFinder (R)]

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Type
research article
DOI
10.1016/S0040-4039(98)80025-7
Author(s)
Laib, Taoues
•
Zhu, Jieping  
Date Issued

1999

Publisher

Elsevier

Published in
Tetrahedron Letters
Volume

40

Issue

1

Start page

83

End page

86

Subjects

Asymmetric synthesis and induction (asym. total synthesis of sanjoinine G1)

•

asym total synthesis sanjoinine G1

Note

CAN 130:209969

34-3

Amino Acids, Peptides, and Proteins

Institut de Chimie des Substances Naturelles, CNRS,Gif-sur-Yvette,Fr.

Journal

written in English.

217495-61-9P; 221004-72-4P; 221004-77-9P Role: BYP (Byproduct), PREP (Preparation) (asym. total synthesis of sanjoinine G1); 10148-70-6 ((2S,3S)-3-Hydroxyleucine); 17469-89-5 (N,N-Dimethyl-L-phenylalanine); 221004-71-3 Role: RCT (Reactant), RACT (Reactant or reagent) (asym. total synthesis of sanjoinine G1); 87421-21-4P; 202478-35-1P; 221004-68-8P; 221004-69-9P; 221004-70-2P; 221004-73-5P; 221004-74-6P; 221004-75-7P; 221004-76-8P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (asym. total synthesis of sanjoinine G1); 107462-36-2P (Sanjoinine G1) Role: SPN (Synthetic preparation), PREP (Preparation) (asym. total synthesis of sanjoinine G1)

Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPN  
Available on Infoscience
November 25, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/58528
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