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research article
An Iron Carbonyl Pyridonate Complex Related to the Active Site of the [Fe]-Hydrogenase (Hmd)
2009
A mononuclear iron bis(carbonyl) pyridonate complex (1), which exhibits several common structural features with the active site of the iron−sulfur cluster-free [Fe]- hydrogenase, was synthesized and characterized. Spectroscopic data of 1 suggests a 2+ oxidation state for the Fe ion in the [Fe]-hydrogenase. Complex 1 serves as a precursor to other hydrogenase models.
Type
research article
Web of Science ID
WOS:000265166300023
Authors
Obrist, Blaise V.
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Ahrens, Anne
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Schünemann, Volker
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•
Publication date
2009
Published in
Volume
48
Issue
8
Start page
3514
End page
3516
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
March 20, 2009
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