Solid-state dye-sensitized solar cells currently suffer from issues such as inadequate nanopore filling, low conductivity and crystallization of hole-transport materials infiltrated in the mesoscopic TiO2 scaffolds, leading to low performances. Here we report a record 11% stable solid-state dye-sensitized solar cell under standard air mass 1.5 global using a hole-transport material composed of a blend of Cu (4,40,6,60-tetramethyl-2,20-bipyridine)22 and Cu (4,40,6,60-tetramethyl-2,20 bipyridine)2. The amorphous Cu(II/I) conductors that conduct holes by rapid hopping infiltrated in a 6.5 mm-thick mesoscopic TiO2 scaffold are crucial for achieving such high efficiency. Using time-resolved laser photolysis, we determine the time constants for electron injection from the photoexcited sensitizers Y123 into the TiO2 and regeneration of the Y123 by Cu(I) to be 25 ps and 3.2 ms, respectively. Our work will foster the development of low-cost solid-state photovoltaic based on transition metal complexes as hole conductors.