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research article

Structural study of nickelate based heterostructures

Varbaro, Lucia
•
Mundet, Bernat
•
Bandyopadhyay, Subhadeep
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March 1, 2024
Apl Materials

Heterostructures consisting of SmNiO3 and NdNiO3 alternating layers with additional LaAlO3 spacer layers were grown and fully characterized by means of x-ray diffraction, atomic force microscopy, and scanning transmission electron microscopy. A change in the orientation of the orthorhombic long-axis of the nickelate layers is observed when a single unit cell of LaAlO3 is inserted between SmNiO3 and NdNiO3, in agreement with density functional theory calculations. At the same time, the structure of the ultra-thin rhombohedral LaAlO3 layers is affected by their proximity to orthorhombic nickelate layers, with both scanning transmission electron microscopy studies and density functional theory calculations revealing a weak antipolar motion of the La-cation in the LaAlO3 layers that is not present in the bulk rhombohedral structure of this compound.

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Type
research article
DOI
10.1063/5.0184306
Web of Science ID

WOS:001180028900002

Author(s)
Varbaro, Lucia
Mundet, Bernat
Bandyopadhyay, Subhadeep
Dominguez, Claribel
Fowlie, Jennifer
Korosec, Lukas
Hsu, Chih-Ying  
Alexander, Duncan T L  
Ghosez, Philippe
Triscone, Jean-Marc
Date Issued

2024-03-01

Publisher

Aip Publishing

Published in
Apl Materials
Volume

12

Issue

3

Article Number

031104

Subjects

Technology

•

Physical Sciences

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSME  
FunderGrant Number

Swiss National Science Foundation-Division II

200020_179155

Available on Infoscience
April 3, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/206879
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