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  4. Combined Vacuum Evaporation and Solution Process for High-Efficiency Large-Area Perovskite Solar Cells with Exceptional Reproducibility
 
research article

Combined Vacuum Evaporation and Solution Process for High-Efficiency Large-Area Perovskite Solar Cells with Exceptional Reproducibility

Tan, Liguo
•
Zhou, Junjie
•
Zhao, Xing
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February 17, 2023
Advanced Materials

Organic-inorganic hybrid perovskites exhibit outstanding performances in perovskite solar cells (PSCs). However, the complex solution chemistry of perovskites precursors renders it difficult to prepare large-area devices in a reproducible way, which is a prerequisite for the technology to make an impact beyond lab scale. Vacuum processing, instead, is an established technology for large-scale coating of thin films. However, with respect to the hybrid perovskites it is highly challenging due to the high vapor pressure of the organic ammonium halide. In this work, vacuum evaporation of lead iodide and solution processing of organic ammonium halide is combined to produce large-area homogeneous perovskite films with large grains in a highly reproducible way. The resulting PSCs achieve a power conversion efficiency (PCE) of 24.3% (certified 23.9%) on small area (0.10 cm(2)), 24.0% (certified 23.7%) on large area (1 cm(2)) and 20.0% for minimodule (16 cm(2)), and maintain 90% of its initial efficiency after 1000 h 1-sun operation. The vacuum evaporation prevents advert environmental effects on lead halide formation and guarantees a reproducible fabrication of high-quality large-area perovskite films, which opens a promising way for large-scale fabrication of perovskite optoelectronics.

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Type
research article
DOI
10.1002/adma.202205027
Web of Science ID

WOS:000934694700001

Author(s)
Tan, Liguo
Zhou, Junjie
Zhao, Xing
Wang, Siyang
Li, Minghao
Jiang, Chaofan
Li, Hang
Zhang, Yu
Ye, Yiran
Tress, Wolfgang
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Date Issued

2023-02-17

Publisher

Wiley-V C H Verlag Gmbh

Published in
Advanced Materials
Volume

35

Issue

13

Article Number

2205027

Subjects

Chemistry, Multidisciplinary

•

Chemistry, Physical

•

Nanoscience & Nanotechnology

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Materials Science, Multidisciplinary

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Physics, Applied

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Physics, Condensed Matter

•

Chemistry

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Science & Technology - Other Topics

•

Materials Science

•

Physics

•

high efficiency

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large-area

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perovskite solar cells

•

vacuum evaporation

•

fabrication

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deposition

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
March 13, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/195825
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