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research article

Hopping and trapping mechanisms in organic field-effect transistors

Konezny, S.J.
•
Bussac, M.N.  
•
Zuppiroli, L.  
2010
Physical Review B

A charge carrier in the channel of an organic field-effect transistor (OFET) is coupled to the electric polarization of the gate in the form of a surface Fröhlich polaron [N. Kirova and M. N. Bussac, Phys. Rev. B 68, 235312 (2003)]. We study the effects of the dynamical field of polarization on both small-polaron hopping and trap-limited transport mechanisms. We present numerical calculations of polarization energies, band- narrowing effects due to polarization, hopping barriers, and interface trap depths in pentacene and rubrene transistors as functions of the dielectric constant of the gate insulator and demonstrate that a trap-and-release mechanism more appropriately describes transport in high-mobility OFETs. For mobilities on the order 0.1 cm^2/V s and below, all states are highly localized and hopping becomes the predominant mechanism.

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Type
research article
DOI
10.1103/PhysRevB.81.045313
Web of Science ID

WOS:000274002500075

Author(s)
Konezny, S.J.
Bussac, M.N.  
Zuppiroli, L.  
Date Issued

2010

Published in
Physical Review B
Volume

81

Article Number

045313

Subjects

PACS numbers: 72.80.Le, 71.38.Fp, 72.20.Jv

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LOMM  
Available on Infoscience
January 19, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/45586
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