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  4. Comparing spiro-OMeTAD and P3HT hole conductors in efficient solid state dye-sensitized solar cells
 
research article

Comparing spiro-OMeTAD and P3HT hole conductors in efficient solid state dye-sensitized solar cells

Yang, Lei
•
Cappel, Ute B.
•
Unger, Eva L.
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2012
Physical Chemistry Chemical Physics

Two hole conductor materials, spiro-OMeTAD and poly(3-hexylthiophene) (P3HT), were compared in solid-state dye-sensitized solar cells. Two org. dyes contg. one anchor unit (D35) or two anchor units (M3) were used in the comparison. Absorbed photon-to-current conversion efficiency close to unity was obtained for the devices with spiro-OMeTAD. Energy conversion efficiencies of 4.7% and 4.9% were measured for the devices with spiro-OMeTAD and the dyes D35 and M3, resp. For the devices using the P3HT hole conductor the results were rather different comparing the two dye mols., with energy conversion efficiencies of 3.2% and 0.5% for D35 and M3, resp. Photoinduced absorption measurements suggest that the regeneration of the dyes, and the polymer infiltration, is not complete using P3HT, while spiro-OMeTAD regenerates the dyes efficiently. However, the TiO2/D35/P3HT system shows rather high energy conversion efficiency and electrochem. oxidn. of the dyes on TiO2 indicates that D35 has a more efficient dye-to-dye hole conduction than M3, which thereby might explain the higher performance. The dye hole conduction may therefore be of significant importance for optimizing the energy conversion in such hybrid TiO2/dye/polymer systems.

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Type
research article
DOI
10.1039/C1CP23031J
Author(s)
Yang, Lei
Cappel, Ute B.
Unger, Eva L.
Karlsson, Martin
Karlsson, Karl Martin
Gabrielsson, Erik
Sun, Licheng
Boschloo, Gerrit
Hagfeldt, Anders  
Johansson, Erik M. J.
Date Issued

2012

Published in
Physical Chemistry Chemical Physics
Volume

14

Start page

779

End page

789

Subjects

spirobifluorene polyhexylthiophene hole conductor dye sensitized solar cell

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPM  
Available on Infoscience
July 6, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/115868
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