Complexes of a transition metal with 2,2-bipyridine ligands substituted by at least one ammonium alkyl radical, process for their fabrication and their use as redox mediator
Complex of general formula I <IMAGE> in which R1, R2 and R3, which may be identical or different, represent separately a linear or branched alkyl radical of 1 to 5 carbon atoms, or, together with the nitrogen atom to which they are attached, a heterocyclic radical having 5 to 7 carbon atoms; "alk" represents a linear or branched alkylene radical having 1 to 5 carbon atoms; R4 to R8, which may be identical or different, represent hydrogen, a hydroxyl, alkoxy or aryloxy group, a primary, secondary or tertiary amino group, or the group -alk-N<+)<R1R2R3) in which "alk", R1, R2 and R 3 have the above meanings; M represents a transition metal such as Fe, Ru or Os; X represents an anion and n represents an integer corresponding to the number of positive charges of the complex.
9436701
Alternative title(s) : (de) Komplexe eines übergangsmetalls mit 2,2-bipyridin-liganden, die mit mindestens einer ammoniumalkylgruppe substituiert sind, verfahren zu ihrer herstellung und ihre anwendung als redoxvermittler. (fr) Complexes d'un métal de transition à ligands 2,2-bipyridine substitués par au moins un radical ammonium alkyle, leur procédé de fabrication et leur application comme médiateur redox. (en) Complexes of a transition metal with 2,2-bipyridine ligands substituted by at least one ammonium alkyl radical, process for their fabrication and their use as redox mediator.
DOI | Country code | Kind code | Date issued |
JP3751032 | JP | B2 | 2006-03-01 |
CA2110828 | CA | C | 2005-02-15 |
DE69324217 | DE | T2 | 1999-11-04 |
DE69324217 | DE | D1 | 1999-05-06 |
AT178333 | AT | T | 1999-04-15 |
EP0602488 | EP | B1 | 1999-03-31 |
AU665327 | AU | B2 | 1995-12-21 |
FR2699170 | FR | B1 | 1995-07-28 |
US5410059 | US | A | 1995-04-25 |
JPH06263781 | JP | A | 1994-09-20 |
AU5240493 | AU | A | 1994-08-04 |
KR940014424 | KR | A | 1994-07-18 |
EP0602488 | EP | A1 | 1994-06-22 |
FR2699170 | FR | A1 | 1994-06-17 |
CA2110828 | CA | A1 | 1994-06-16 |