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research article

Phonon anomaly at the charge ordering transition in 1T-TaS2

Gasparov, L. V.
•
Brown, K. G.
•
Wint, A. C.
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2002
Physical Review B

The infrared reflectance of the transition-metal chalcogenide 1T-TaS2 has been measured at temperatures from 30 K to 360 K over 30-45 000 cm(-1) (4 meV-5.5 eV). The optical conductivity was obtained by Kramers-Kronig analysis. At 360 K only modest traces of the phonon lines are noticeable. The phonon modes are followed by a pseudo-gap-like increase of the optical conductivity, with direct optical transitions observed at frequencies above 1 eV. As the temperature decreases, the low-frequency conductivity also decreases, phonon modes become more pronounced, and a pseudogap develops into a gap at 800 cm(-1) (100 meV). We observe an anomalous frequency dependence of the 208 cm(-1) infrared-active phonon mode. This mode demonstrates softening as the temperature decreases below the 180-K transition. The same mode demonstrates strong hysteresis of the frequency and linewidth changes, similar in its temperature behavior to the hysteresis in the dc resistivity. We discuss a possible relation of the observed softening of the mode to the structural changes and changes in electronic properties associated with the 180-K transition.

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Type
research article
DOI
10.1103/PhysRevB.66.094301
Web of Science ID

WOS:000178383200051

Author(s)
Gasparov, L. V.
Brown, K. G.
Wint, A. C.
Tanner, D. B.
Berger, H.  
Margaritondo, G.  
Gaal, R.  
Forro, L.  
Date Issued

2002

Published in
Physical Review B
Volume

66

Issue

9

Article Number

094301

Subjects

RAMAN-SCATTERING

•

SUPERCONDUCTING GAP

•

SINGLE-CRYSTALS

•

YBA2CU3O7-DELTA

•

DICHALCOGENIDES

•

INTENSITY

Note

Univ N Florida, Dept Chem & Phys, S Jacksonville, FL 32224 USA. Univ Florida, Dept Phys, Gainesville, FL 32611 USA. Ecole Polytech Fed Lausanne, Inst Phys Complex Matter, CH-1015 Lausanne, Switzerland. Gasparov, LV, Univ N Florida, Dept Chem & Phys, 4567 St Johns Bluff Rd, S Jacksonville, FL 32224 USA.

ISI Document Delivery No.: 600GX

094301

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
LPRX  
Available on Infoscience
October 3, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/234877
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