Metallierung allylständiger Methylen- und Methin-Gruppen
Metalation of cyclohexene by Me3SiCH2K, then treatment with ethylene oxide gave 83% 2-cyclohexene-1-ethanol. Similarly, Me2CHCH:CH2 gave 37% Me2C:CH(CH2)3OH and 28% CH2:CHCMe2CH2CH2OH. [on SciFinder (R)]
1975
5
328
329
CAN 83:58913
29-2
Organometallic and Organometalloidal Compounds
Inst. Chim. Org.,Univ. Lausanne,Lausanne,Switz.
Journal
written in German.
110-83-8 Role: RCT (Reactant), RACT (Reactant or reagent) (allylic metalation of, by [(trimethylsilyl)methyl]potassium); 53127-82-5 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation of cyclohexene and 3-methyl-1-butene by); 563-45-1 Role: RCT (Reactant), RACT (Reactant or reagent) (metalation of, by [(trimethylsilyl)methyl]potassium); 16452-34-9P; 42272-94-6P; 53589-56-3P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
REVIEWED
EPFL