Planning a kinetic and mechanistic study with cerium(IV)
In this paper, the authors will describe an acidic sulfate medium in which various concentrations of the possible Ce(IV) species can be prescribed. Secondly, they present the computations-based on simultaneous solutions of various equilibrium of the concentration distributed of the sulfato and hydroxo species of Ce(IV). Lastly, the optimum planning of a kinetic study of a Ce(IV)-reductant system, based on the quantitative description of the medium is suggested.
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Hanna, S. B., Kessler, R. R., Merbach, A., & Ruzicka, S. (1976). Planning a kinetic and mechanistic study with cerium(IV). Journal of Chemical Education, 53(8), 524–527. https://doi.org/10.1021/ed053p524
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1976
53
8
524
527
REVIEWED
EPFL