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  4. The hydrogen isotope composition of seawater and the global water cycle
 
conference paper

The hydrogen isotope composition of seawater and the global water cycle

Gillet, P.  
•
Robert, F.
•
Lecuyer, C.
1998
Chemical Geology
Workshop on Geochemical Earth Reference Model

Long-term evolution of the Earth's water cycle is investigated to predict potential variations in the hydrogen stable isotope composition of seawater. Mass balance calculations are used to estimate the delta D value of the early ocean before storage of water (about 20% of the present-day size) in the biosphere, cryosphere, sediments, and metamorphic rocks. The early ocean was plausibly deuterium-depleted (delta D = -18 +/- 6 parts per thousand) in comparison with the present-day oceans (delta D = 0 parts per thousand). A kinetic treatment of the long-term water cycle suggests that hydrogen isotope variations of the oceans may have occurred at a Ga time-scale in response to the imbalance between fluxes of water trapped at ridges and released along subduction zones. Two limiting cases are observed: (1) the delta D value of the oceans does not exceed a value of + 10 parts per thousand when the oceanic mass decreases by 20%; and (2) the delta D value decreases down to -20 parts per thousand for a 20% mass increase of the oceans. An increase in the delta D value of the planet via an addition of extraterrestrial water is restricted to 7 parts per thousand since 3.5 Ga. The present-day mean D/H ratio of the bulk Earth is calculated to be 149(+/-3) x 10(-6). Since the statistical distribution of the D/H ratios in carbonaceous chondrites exhibits a maximum value around 140 +/- 10 x 10(-6); it is unlikely that the water D/H ratio was significantly fractionated during Earth's accretion relatively to the protosolar water ratio. (C) 1998 Elsevier Science B.V. All rights resented.

  • Details
  • Metrics
Type
conference paper
DOI
10.1016/S0009-2541(97)00146-0
Web of Science ID

WOS:000074301200006

Author(s)
Gillet, P.  
Robert, F.
Lecuyer, C.
Date Issued

1998

Published in
Chemical Geology
Volume

145

Start page

249

End page

261

Subjects

water cycle

•

hydrogen isotopes

•

seawater

•

chondrite

•

Stable-Isotope

•

Oceanic-Crust

•

Upper Mantle

•

Continental-Crust

•

O-18/O-16 Ratios

•

Earths Mantle

•

Morb Glass

•

Carbon

•

Systematics

•

Constraints

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
EPSL  
Event nameEvent placeEvent date
Workshop on Geochemical Earth Reference Model

LYON, FRANCE

Mar, 1996

Available on Infoscience
September 29, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/71324
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