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  4. Determination of pressure-induced valence changes in YbAl2 by resonant inelastic x-ray emission
 
research article

Determination of pressure-induced valence changes in YbAl2 by resonant inelastic x-ray emission

Annese, E.
•
Rueff, J. P.
•
Palenzona, A.
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2003
Physical Review B

Novel x-ray spectroscopies such as high-resolution x-ray absorption (XAS) performed in the partial fluorescence yield mode (PFY), and resonant emission (RXES) offer new opportunities to probe the bulk electronic configuration in strongly correlated systems. We performed an Yb L-3 PFY-XAS and RXES investigation of the intermediate valence compound YbAl2 under external pressure. We found that the Yb valence increases from 2.25 at ambient pressure to 2.9 at 385 kbar. This experiment has extended the range of pressures explored until now, in order to cover the whole valence transition, which we find to be completed around 200 kbar. Moreover, the new data considerably reduce the experimental error bars on previous estimates and provide the most accurate description to date of this transition. We discuss the relative merits of various approaches to extract the 4f occupancy from the spectroscopic data.

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Type
research article
DOI
10.1103/PhysRevB.68.245114
Web of Science ID

WOS:000188391900037

Author(s)
Annese, E.
Rueff, J. P.
Palenzona, A.
Vanko, G.
Braicovich, L.
Shukla, A.
Grioni, M.  
Dallera, C.
Date Issued

2003

Published in
Physical Review B
Volume

68

Article Number

245114

Subjects

Mean-Field Theory

•

Absorption-Spectroscopy

•

Raman-Scattering

•

Photoemission-Spectroscopy

•

Intermetallic Compounds

•

Temperature-Dependence

•

Electronic-Structure

•

Pseudobinary Alloys

•

Ce Compounds

•

L(3) Edge

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
April 7, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/49198
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